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Material Safety Data Sheets

Material Safety Data Sheet: Graniterock Oil Seal

Section 1: Product Information

Trade Name: Graniterock Oil Seal
Producer's Name: Graniterock Company
Address: 365 Blomquist Street
Redwood City, CA 94063-2701
Emergency Phone Number: 831.768.2000
MSDS Last Revised: April 2003
MSDS Effective Date: April 2003
Prepared by: Paul Lessard, PhD
This MSDS has been compiled in accordance with OSHA's Hazcom Standard (29 CFR 1910.1200)

Section 2: Composition/Information on the Components

Chemical Names CAS Number Concentration
Acetaldehyde 75-07-0 < 0.05%
Vinyl acetate 108-05-4 < 0.25%
Acrylic monomer(s) N/A < 0.5%

Section 3: Hazard Identification

Routes of Entry: Eyes - Ingestion - Inhalation - Skin
Carcinogenic Status: Vinyl acetate is listed by the International Agency for Research on Cancer (IARC) as a possible cancer causing agent.
Health Effects - Eyes: May cause slight irritation to eyes.
Health Effects - Skin: Prolonged or repeated contact can cause irritation.
Health Effects - Inhalation: Inhalation of vapors may cause headaches or nausea.

Section 4: First Aid Measures

First Aid - Eyes: Immediately flush with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention if soreness or redness persists.
First Aid - Skin: Wash with soap and water. Remove contaminated clothing. Contaminated clothing should be washed or dry-cleaned before re-use. Obtain medical attention if irritation or redness persists.
First Aid - Ingestion: If swallowed, give two glasses of water. Consult a physician.

Section 5: Fire Fighting Measures

Extinguishing Media: Not flammable. Use appropriate extinguishing media for containers in the surrounding area.
Unusual Fire & Explosion Hazards: Dried material can burn.
Protective Equipment for Fire-Fighting: Wear full protective clothing and self-contained breathing apparatus.

Section 6: Accidental Release Measures

Engineering Control Measures: Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions. If engineering controls and work practices are not effective in preventing or controlling exposure, then suitable personal protective equipment should be used.
Respiratory Protection: Respiratory protection if there is a risk of uncontrolled exposure to vapors. A respiratory protection program meeting OSHA 1910.134 requirements must be followed whenever workplace conditions warrant respirator use.
Hand Protection: Neoprene-type gloves.
Eye Protection: Chemical splash goggles.

Section 7: Handling & Storage
Prevent material from freezing by maintaining temperatures above 34?F. Do no store above 120?F. Vinyl acetate monomer and/or acetaldehyde vapors may be evolved when product is heated during installation or placement. Lack of adequate ventilation may result in airborne levels above established exposure limits (Section 8). Monitor the workplace if ventilation is questionable.

Section 8: Exposure Controls/Personal Protection

OSHA ACGIH
TWA STEL TWA STEL
  Vinyl acetate 10 20 10 20
  Acetaldehyde 100 2150 100 150

Spill Procedures: Contain spills immediately with inert materials such as sand or soil. Transfer liquids and inert cleanup materials to separate suitable containers for disposal.
Personal Precautions: Wear appropriate protective clothing. Wear respiratory protection.
Environmental Precautions: No specific measures necessary.

Section 9: Physical and Chemical Properties

Physical State: Liquid
Color: Milky
Odor: Sweet
pH: 4.5–5.5
Specific Gravity: 1.0–1.2
Boiling Range/Point (°F): 212°F
Melting Point (°F): 32°F
Flash Point (PMCC) (°C/F): Not Flammable
Vapor Pressure: 17 mm Hg @68°F
Solubility in Water: Dispersable
Vapor Density (Air = 1): < 1

Section 10: Stability and Reactivity

Stability: Stable unless heated to temperatures greater than 350°F where thermal decomposition will begin.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: Thermal decomposition may yield acrylic monomers and/or vinyl acetate monomer(s).

Section 11: Toxicological Information

Reproductive/Developmental Toxicity: No relevant studies identified. This product is not expected to cause reproductive or developmental health effects.

Section 12: Ecological Information

Mobility: No relevant studies identified.
Persistence/Degradability: No relevant studies identified.
Bio-accumulation: Product is not expected to bioaccumulate.
Ecotoxicity: Product is not expected to be toxic to birds, fish, invertebrates, microorganisms or plants.

Section 13: Disposal
Coagulate the emulsion by stepwise addition of ferric chloride and lime. Remove clear liquid and incinerate contaminated solids in accordance with local, state, and federal regulations.

Section 14: Transport Information

US DOT: Not Regulated

Section 15: Regulatory Information

TSCA Listing
California Proposition 65
This product contains the following materials, which the State of California has found to cause cancer:

  • Acetaldehyde (75-07-0)
  • Formaldehyde gas (50-00-0)

SARA Title III Sect. 313
This product contains a chemical which is listed in Section 3133 at or above de minimis concentrations:
Vinyl acetate (108-05-4)

CERCLA Information (40CFR 372)
This material contains no hazardous or extremely hazardous substances as defined by CERCLA or SATA Title III.

Section 16: Other Information

Abbreviations
N/A: Denotes no applicable information found or available
AS#: Chemical Abstracts Service Number
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
NTP: National Toxicology Program
IARC: International Agency for Research on Cancer
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%

Graniterock Company Disclaimer
The information contained in this MSDS is based on tests, experience and other information which Graniterock Company believes reliable and is supplied for information purposes only. Since conditions of use are outside of our control, Graniterock Company disclaims any liability for damage or injury which results from use of the above information. Nothing contained herein shall constitute a guarantee, warranty (including warranty of merchantability) or representation (including freedom from patent liability) by Granite Rock Company with respect o the information, the material described, or its use for any specific purpose, even if that purpose is known to Graniterock Company.

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